CESL Trip to Toyota Motor Manufacturing, Kentucky, Inc.
Eighteenth Annual Dawson Lecture
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Dr. Geoffrey Coates of Cornell University will be presenting a seminar titled "New Polymers from Old Monomers: Advances Enabled through Catalyst Design." He will also participate as a judge for this year's Regional Poster Competition held in CP-114 from 1-3 pm.
Abstract: Although the chemical, physical, and mechanical properties of a polymer are the most vital factors in determining utility, another important constraint that must be considered is the cost of the material. The best way to create inexpensive new polymers is to start with large-scale commodity monomers, rather than rely on the development of new-to-the-world monomers. The focus of our work is the development of new synthetic methods for polymer synthesis, where known organic feedstocks are combined in alternative ways to make new macromolecular materials. We accomplish this through the development of metal-based catalysts that exhibit unique reactivity. In this presentation, the discovery, development and application of new catalysts for polymerization will be presented. The development of new methods for the synthesis of sustainable polymers will also be discussed.
For more information about the Dawson Lecture Series, click here.
Faculty Host: Dr. Susan Odom
Discourses, Discontinuities, and the Urban Episteme: The City in Latin American Cultural Thought
Chemistry Department Seminar
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Etienne Garand will be presenting a seminar titled Probing catalytic reaction intermediates using cryogenic ion vibrational spectroscopy.
Abstract: Understanding reaction pathways and mechanisms is vitally important for the rational design of catalysts. Toward that end, we developed a method based on mass spectrometry and cryogenic ion vibrational spectroscopy to capture and characterize the reaction complexes formed during homogeneous catalytic reactions. In addition to experimental considerations, this talk will present recent work on model metal hydroxide complexes and the first application of our approach to study catalytic water oxidation. We show that vibrational spectroscopy of the model M2+OH- (M=Mn-Zn) systems can be used to study the trends in the extent of charge transfer between ligand and the metal center. Such systematic studies elucidate on the behaviors observed in the IR spectra of transition metal species and provide a framework for the analysis of more complex spectra. To probe reaction intermediates, we coupled an in-line electrochemical flow cell to our electrospray ionization source, thereby allowing us to controllably reach each step in the catalytic cycle. Using this source, we have successfully isolated the first few reaction intermediates in water oxidation catalyzed by the single metal center [Ru(tpy)(bpy)(H2O)]2+ catalyst. Moreover, using vibrational predissociation spectroscopy, we characterized the structure of these species as well as their microsolvated clusters. The results show that the solvent hydrogen-bond network around the active site can play an active role in the reaction.
Faculty Host: Dr. Dong-Sheng Yang
Development of an Extraction Method for the Mass Spectral Analysis of Organic Gunshot Residue from Clothing
Molecular mechanisms that control development and dysfunction of the mammalian cerebellum
Host: Brian Rymond, University of Kentucky
The College of Arts and Sciences in collaboration with the College of Agriculture & the Graduate School is sponsoring this graduate seminar course. Two of the seminars will be held in the Biology Department (TH Morgan Building) and two will be held in the Plant Sciences Building (College of Agriculture).
Neuronal regeneration and degeneration in long-lived Drosophila larvae
Host: Brian Rymond, University of Kentucky
The College of Arts and Sciences in collaboration with the College of Agriculture & the Graduate School is sponsoring this graduate seminar course. Two of the seminars will be held in the Biology Department (TH Morgan Building) and two will be held in the Plant Sciences Building (College of Agriculture).
Coding and Decoding Calcium Signals in Plants
Host: Seth DeBolt, University of Kentucky
The College of Arts and Sciences in collaboration with the College of Agriculture & the Graduate School is sponsoring this graduate seminar course. Two of the seminars will be held in the Biology Department (TH Morgan Building) and two will be held in the Plant Sciences Building (College of Agriculture).
Molecular, genetic and biochemical approaches to understanding and improving tomato flavor
Host: Seth DeBolt, University of Kentucky
The College of Arts and Sciences in collaboration with the College of Agriculture & the Graduate School is sponsoring this graduate seminar course. Two of the seminars will be held in the Biology Department (TH Morgan Building) and two will be held in the Plant Sciences Building (College of Agriculture).