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Coherent band excitations in CePd<sub>3</sub>: A comparison of neutron scattering and ab initio theory.

Author
Abstract
:

In common with many strongly correlated electron systems, intermediate valence compounds are believed to display a crossover from a high-temperature regime of incoherently fluctuating local moments to a low-temperature regime of coherent hybridized bands. We show that inelastic neutron scattering measurements of the dynamic magnetic susceptibility of CePd3 provides a benchmark for ab initio calculations based on dynamical mean field theory. The magnetic response is strongly momentum dependent thanks to the formation of coherent f-electron bands at low temperature, with an amplitude that is strongly enhanced by local particle-hole interactions. The agreement between experiment and theory shows that we have a robust first-principles understanding of the temperature dependence of f-electron coherence.

Year of Publication
:
2018
Journal
:
Science (New York, N.Y.)
Volume
:
359
Issue
:
6372
Number of Pages
:
186-191
Date Published
:
2018
ISSN Number
:
0036-8075
DOI
:
10.1126/science.aan0593
Short Title
:
Science
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