Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction.
| Author | |
|---|---|
| Abstract |
:
Trimethylsilylethynyl ketones can be desilylated in the presence of a tethered carbon diacid and induced to undergo a double Michael reaction in situ. The trimethylsilylethynyl ketones can serve as surrogates of ethynyl ketones that are difficult to prepare or isolate. |
| Year of Publication |
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2002
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| Journal |
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The Journal of organic chemistry
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| Volume |
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67
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| Issue |
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9
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| Number of Pages |
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3149-51
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| Date Published |
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2002
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| ISSN Number |
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0022-3263
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| URL |
:
https://dx.doi.org/10.1021/jo0163086
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| DOI |
:
10.1021/jo0163086
|
| Short Title |
:
J Org Chem
|
| Download citation |