Real-time atomistic observation of structural phase transformations in individual hafnia nanorods.
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| Abstract | :  High-temperature phases of hafnium dioxide have exceptionally high dielectric constants and large bandgaps, but quenching them to room temperature remains a challenge. Scaling the bulk form to nanocrystals, while successful in stabilizing the tetragonal phase of isomorphous ZrO, has produced nanorods with a twinned version of the room temperature monoclinic phase in HfO. Here we use in situ heating in a scanning transmission electron microscope to observe the transformation of an HfO nanorod from monoclinic to tetragonal, with a transformation temperature suppressed by over 1000°C from bulk. When the nanorod is annealed, we observe with atomic-scale resolution the transformation from twinned-monoclinic to tetragonal, starting at a twin boundary and propagating via coherent transformation dislocation; the nanorod is reduced to hafnium on cooling. Unlike the bulk displacive transition, nanoscale size-confinement enables us to manipulate the transformation mechanism, and we observe discrete nucleation events and sigmoidal nucleation and growth kinetics. | 
| Year of Publication | :  2017 | 
| Journal | :  Nature communications | 
| Volume | :  8 | 
| Number of Pages | :  15316 | 
| Date Published | :  2017 | 
| URL | :  https://doi.org/10.1038/ncomms15316 | 
| DOI | :  10.1038/ncomms15316 | 
| Short Title | :  Nat Commun | 
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